The ozone resistance of blends of natural rubber (NR) and ethylene/propylene rubber (EPM) was quantitatively assessed in terms of critical stress-strain parameters. The effects of blend ratio and addition of carbon black and china clay on ozone resistance were also studied. It is observed that resistance of NR vulcanisates to ozone cracking is remarkably improved by blending it with EPM rubber. A blend ratio in the range of 80: 20 to 70: 30 NR : EPM is found to give adequate protection against ozone attack. Addition of high abrasion furnace (HAF) black improves ozone resistance of NR and the blends. Blending of HAF black masterbatches of the two polymers is beneficial only when the proportion of EPM is more than 30 parts per hundred rubber (phr). Addition of china clay reduces ozone resistance of natural rubber and the blends drastically.
Ozone resistance, Polymer blends, NR/EPM blends, Masterbatch, Carbon black, China clay, Critical stress, Critical strain, Critical stored elastic energy density